Overtone pa.m
Overtone soft pulse-acquire experiment. Syntax:
spectrum=overtone_pa(spin_system,parameters,H,R,K)
where H is the hamiltonian commutation superoperator, R is the relaxation superoperator and K is the chemical kinetics superoperator. The following parameters are required:
parameters.sweep vector with two elements giving
the spectrum frequency extents
in Hz around the overtone frequency
parameters.npoints number of points in the spectrum
parameters.rho0 initial state
parameters.coil detection state
parameters.Lx
parameters.Ly X and Y Zeeman operators on the
quadrupolar nucleus
parameters.rf_frq pulse frequency offset from
the overtone frequency on the
quadrupolar nucleus, Hz
parameters.rf_pwr pulse power on the quadrupolar
nucleus, Hz
parameters.rf_dur pulse duration, seconds
parameters.method 'average' uses the average Hamil-
tonian theory, 'fplanck' uses
Fokker-Planck formalism
Relaxation must be present in the system dynamics, or the matrix inversion operation below would fail to converge. The relaxation matrix should *not* be thermalized.