Difference between revisions of "Dqf cosy.m"

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Phase-sensitive double-quantum filtered COSY pulse sequence. Syntax:
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{{DISPLAYTITLE:dqf_cosy.m}} __NOTOC__
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Phase-sensitive double-quantum filtered COSY pulse sequence.
  
              fid=dqf_cosy(spin_system,parameters,H,R,K)
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==Syntax==
  
where H is the Hamiltonian commutation superoperator, R is the relaxa-
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    fid=dqf_cosy(spin_system,parameters,H,R,K)
tion superoperator, K is chemical kinetics superoperator and the output
 
has fid.cos and fid.sin fields to facilitate subsequent hypercomplex
 
processing. The following parameters are required:
 
  
  parameters.sweep              sweep width in Hz
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==Parameters==
  
  parameters.npoints           number of points for both dimensions
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    parameters.sweep        sweep width in Hz
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    parameters.npoints     number of points for both dimensions
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    parameters.spins        nuclei on which the sequence runs,
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                            specified as {'1H'}, {'13C'}, etc.
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    H  - Hamiltonian matrix, received from context function
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    R  - relaxation superoperator, received from context function
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    K  - kinetics superoperator, received from context function
  
  parameters.spins              nuclei on which the sequence runs,
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==Outputs==
                                specified as '1H', '13C', etc.
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    fid.cos, fid.sin  -  components of the free induction
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                        decay for hypercomplex processing
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==Examples==
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A DQF-COSY spectrum of strychnine (examples/nmr_liquids/dqf_cosy_strychnine.m) appears below.
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[[File:dqf_cosy_strychnine.png]]
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==Notes==
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The double-quantum filter is implemented as an exact analytical coherence-order projection, not as an explicit phase cycle or finite-gradient selection block.
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==See also==
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[[noesy.m]], [[hsqc.m]], [[hmqc.m]], [[hnco.m]], [[hncoca.m]], [[tocsy.m]], [[roesy.m]], [[clip_hsqc.m]], [[coloc.m]], [[cosy.m]], [[crazed.m]], [[ct_cosy.m]], [[ct_hsqc.m]], [[dept.m]], [[deptq.m]], [[ecosy.m]], [[hetcor.m]], [[hmbc.m]], [[hoesy.m]], [[inadequate.m]], [[inadequate_2d.m]], [[inept.m]], [[inv_rec.m]], [[mqs.m]], [[mqs_refocus.m]], [[pansy_cosy.m]], [[pansy_triple.m]], [[sat_rec.m]], [[Built-in_experiments]]
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''Version 2.3, authors: [[Ilya Kuprov]], [[Luke Edwards]]''

Latest revision as of 19:36, 6 June 2026

Phase-sensitive double-quantum filtered COSY pulse sequence.

Syntax

    fid=dqf_cosy(spin_system,parameters,H,R,K)

Parameters

   parameters.sweep        sweep width in Hz

   parameters.npoints      number of points for both dimensions

   parameters.spins        nuclei on which the sequence runs,
                           specified as {'1H'}, {'13C'}, etc.

   H  - Hamiltonian matrix, received from context function

   R  - relaxation superoperator, received from context function

   K  - kinetics superoperator, received from context function

Outputs

   fid.cos, fid.sin  -  components of the free induction
                        decay for hypercomplex processing

Examples

A DQF-COSY spectrum of strychnine (examples/nmr_liquids/dqf_cosy_strychnine.m) appears below.

Dqf cosy strychnine.png

Notes

The double-quantum filter is implemented as an exact analytical coherence-order projection, not as an explicit phase cycle or finite-gradient selection block.

See also

noesy.m, hsqc.m, hmqc.m, hnco.m, hncoca.m, tocsy.m, roesy.m, clip_hsqc.m, coloc.m, cosy.m, crazed.m, ct_cosy.m, ct_hsqc.m, dept.m, deptq.m, ecosy.m, hetcor.m, hmbc.m, hoesy.m, inadequate.m, inadequate_2d.m, inept.m, inv_rec.m, mqs.m, mqs_refocus.m, pansy_cosy.m, pansy_triple.m, sat_rec.m, Built-in_experiments

Version 2.3, authors: Ilya Kuprov, Luke Edwards